Novel three-dimensional cage assembly of a μ4-carbonato-bridged cobalt(II) compound [Co2(bpm)(H2O)2(CO3)(OH)]NO3•4H2O

被引：41

作者：

Armentano, D

De Munno, G ^{[1
]}

Lloret, F

Julve, M

机构：

[1] Univ Calabria, Dipartimento Chim, I-87030 Arcavacata Di Rende, Cosenza, Italy

[2] Univ Valencia, Fac Quim, Dept Quim Inorgan, Burjassot 46100, Valencia, Spain

来源：

INORGANIC CHEMISTRY | 1999年 / 38卷 / 16期

关键词：

D O I：

10.1021/ic981323n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new three-dimensional cobalt(II) complex of formula [Co-2(bpm)(H2O)(2)(CO3)(OH)]NO3. 4H(2)O (1) is obtained from aqueous solutions containing cobalt(II) nitrate hexahydrate, 2,2'-bipyrimidine (bpm), and potassium bicarbonate. The cobalt atoms are bridged by bischelating bpm, single mu(2)-hydroxide, and mu(4)-carbonate groups. Uncoordinated nitrate anions and crystallization water molecules occupy the prismatic holes of the three-dimensional cationic skeleton, and they are held by hydrogen bonds with the hydroxo groups and coordinated water molecules. Variable-temperature magnetic susceptibility measurements reveal the occurrence of an overall antiferromagnetic behavior with a maximum of the susceptibility at 11.5 K.

引用

页码：3744 / +

页数：5

共 35 条

[11] Structural characterization and magnetic properties of the first 2,2′-bipyrimidine-containing iron(III) complexes [J].