Palladium-catalyzed asymmetric alkylation of 2,3-alkadienyl phosphates. Synthesis of optically active 2-(2,3-alkadienyl)malonates

被引：80

作者：

Imada, Y

Ueno, K

Kutsuwa, K

Murahashi, SI

机构：

[1] Osaka Univ, Dept Chem, Grad Sch Engn Sci, Toyonaka, Osaka 5608531, Japan

[2] Okayama Univ Sci, Fac Engn, Dept Chem, Okayama 7000005, Japan

来源：

CHEMISTRY LETTERS | 2002年 / 02期

关键词：

D O I：

10.1246/cl.2002.140

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric alkylation of 2,3-alkadienyl phosphates with soft carbon nucleophiles proceeds efficiently in the presence of palladium complex catalyst bearing MeOBIPHEP or BINAP ligand to give optically active functionalized allenes up to 90% ee.

引用

页码：140 / 141

页数：2

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