Glycerol production and its applications as a raw material: A review

被引:500
作者
Tan, H. W. [1 ]
Aziz, A. R. Abdul [1 ]
Aroua, M. K. [1 ]
机构
[1] Univ Malaya, Fac Engn, Dept Chem Engn, Kuala Lumpur 50603, Malaysia
关键词
Crude glycerol; Tranesterification; Saponification; Hydrolysis; Purification; Glycerol; WASTE COOKING OIL; BIODIESEL PRODUCTION; VEGETABLE-OIL; CRUDE GLYCEROL; TRANSESTERIFICATION; 1,3-PROPANEDIOL; CONVERSION; MICROALGAE; LIPASE; FEEDSTOCKS;
D O I
10.1016/j.rser.2013.06.035
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Glycerol is a valuable byproduct in biodiesel production by transesterification, soap manufacturing by saponification as well as hydrolysis reaction. The purity of glycerol obtained is low due to the presence of impurities such as remaining catalyst, water, soaps, salts and esters formed during the reaction. Purification of glycerol as well as the conversion of glycerol into valuable products has attained growing interest in recent years due to the dramatic growth of the biodiesel industry. This paper reviews different methods of producing crude glycerol as the major by-product. Purification of glycerol was reported as well as value-added products produced from glycerol. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:118 / 127
页数:10
相关论文
共 102 条
[91]   Use of tobacco seed oil methyl ester in a turbocharged indirect injection diesel engine [J].
Usta, N .
BIOMASS & BIOENERGY, 2005, 28 (01) :77-86
[92]   Integrated biodiesel production:: a comparison of different homogeneous catalysts systems [J].
Vicente, G ;
Martínez, M ;
Aracil, J .
BIORESOURCE TECHNOLOGY, 2004, 92 (03) :297-305
[93]  
Voegele E, GLYCERINS ROLE 2009
[94]   Production of biodiesel through transesterification of Jatropha oil using KNO3/Al2O3 solid catalyst [J].
Vyas, Amish P. ;
Subrahmanyam, N. ;
Patel, Payal A. .
FUEL, 2009, 88 (04) :625-628
[95]  
Wall J., 2009, THESIS U IDAHO
[96]   Conversion of glycerol to 1,3-propanediol via selective dehydroxylation [J].
Wang, KY ;
Hawley, MC ;
DeAthos, SJ .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (13) :2913-2923
[97]   Thermodynamic analysis of glycerol partial oxidation for hydrogen production [J].
Wang, Wenju .
FUEL PROCESSING TECHNOLOGY, 2010, 91 (11) :1401-1408
[98]   Thermodynamic Analysis of Glycerin Steam Reforming [J].
Wang, Xiaodong ;
Li, Shuirong ;
Wang, Hao ;
Liu, Bo ;
Ma, Xinbin .
ENERGY & FUELS, 2008, 22 (06) :4285-4291
[99]   Refining of biodiesel by ceramic membrane separation [J].
Wang, Yong ;
Wang, Xingguo ;
Liu, Yuanfa ;
Ou, Shiyi ;
Tan, Yanlai ;
Tang, Shuze .
FUEL PROCESSING TECHNOLOGY, 2009, 90 (03) :422-427
[100]   Acrolein synthesis from glycerol in hot-compressed water [J].
Watanabe, Masaru ;
Lida, Toru ;
Aizawa, Yuichi ;
Aida, Taku M. ;
Inomata, Hiroshi .
BIORESOURCE TECHNOLOGY, 2007, 98 (06) :1285-1290