Synthesis, structure and fluorescence of a 3-D polymer {(Mo4O12)(4,4′-bipy)2}n

被引:21
作者
Cui, CP [1 ]
Dai, JC [1 ]
Du, WX [1 ]
Fu, ZY [1 ]
Hu, SM [1 ]
Wu, LM [1 ]
Wu, XT [1 ]
机构
[1] Chinese Acad Sci Fuzhou, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China
基金
中国国家自然科学基金; 中国科学院基金;
关键词
metal-organic frameworks (MOF); synthesis; crystal structures; TGA-DTA;
D O I
10.1016/S0277-5387(01)00975-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
We report the synthesis, single-crystal X-ray structure, IR, TGA-DTA and fluorescence of a black MOF crystal {(Mo4O12)(4,4'-bipy)(2)}(n), which has two channels. One channel along the [001] direction was formed by a metal-oxygen octatomic ring and the another one along the [010] direction was shaped by 4'4-bipy. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:175 / 179
页数:5
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