A direct route to medium and large cyclic amines from aminoalkenes

被引：20

作者：

Bergmann, DJ ^{[1
]}

Campi, EM ^{[1
]}

Jackson, WR ^{[1
]}

Patti, AF ^{[1
]}

Saylik, D ^{[1
]}

机构：

[1] Monash Univ, Dept Chem, Clayton, Vic 3168, Australia

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 30期

基金：

澳大利亚研究理事会;

关键词：

hydroformylation; regiochemistry; nitrogen heterocycles; medium-ring heterocycles;

D O I：

10.1016/S0040-4039(99)01020-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rhodium-catalysed reactions of aminoalkenes with H-2/CO give cyclic amines with a range of medium and large ring sizes in yields lip to 85%. High regioselectivity for non-branched products can be obtained when BIPHEPHOS is used as a ligand in the hydroformylation reaction. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：5597 / 5600

页数：4