LCA studies comparing biodiesel synthesized by conventional and supercritical methanol methods

被引:93
作者
Kiwjaroun, Choosak [1 ]
Tubtimdee, Chanporn [1 ]
Piumsomboon, Pornpote [1 ]
机构
[1] Chulalongkorn Univ, Fac Sci, Dept Chem Technol, Fuels Res Ctr, Bangkok 10330, Thailand
关键词
Biodiesel; Supercritical methanol; Alkali-catalyzed; Renewable energy; Life cycle assessment; WASTE COOKING OIL; RAPESEED OIL; METHYL ESTERIFICATION; VEGETABLE-OILS; PROCESS MODEL; FATTY-ACIDS; TRANSESTERIFICATION; KINETICS; FUEL; 2-STEP;
D O I
10.1016/j.jclepro.2008.03.011
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Biodiesel is one of the candidates for alternative fuels since it is renewable, sustainable and produced from domestic or non-food crop resources with less detrimental environmental impact. There are several different approaches to the production process. In this paper a new production method, the supercritical methanol process, was investigated and its environmental performance was compared with the conventional alkali-catalyzed process using LCA as a tool. The supercritical process is technically a simpler production process and offers the advantages of higher yields and the production of less environmentally damaging wastes. However, it still generates a significantly higher environmental load since the methanol recovery unit requires a large amount of energy. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:143 / 153
页数:11
相关论文
共 33 条
[1]  
AIZUHAIR S, 2007, BIOFUELS BIOPRODUCTS, V1, P57
[2]   Continuous production of biodiesel via transesterification from vegetable oils in supercritical methanol [J].
Bunyakiat, K ;
Makmee, S ;
Sawangkeaw, R ;
Ngamprasertsith, S .
ENERGY & FUELS, 2006, 20 (02) :812-817
[3]   Analysis of a two-step, noncatalytic, supercritical biodiesel production process with heat recovery [J].
D'Ippolito, S. A. ;
Yori, J. C. ;
Iturria, M. E. ;
Pieck, C. L. ;
Vera, C. R. .
ENERGY & FUELS, 2007, 21 (01) :339-346
[4]   Kinetics of palm oil transesterification in a batch reactor [J].
Darnoko, D ;
Cheryan, M .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2000, 77 (12) :1263-1267
[5]   Noncatalytic alcoholysis kinetics of soybean oil [J].
Dasari, MA ;
Goff, MJ ;
Suppes, GJ .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2003, 80 (02) :189-192
[6]   Biodiesel from vegetable oils via transesterification in supercritical methanol [J].
Demirbas, A .
ENERGY CONVERSION AND MANAGEMENT, 2002, 43 (17) :2349-2356
[7]   Biodiesel from sunflower oil in supercritical methanol with calcium oxide [J].
Demirbas, Ayhan .
ENERGY CONVERSION AND MANAGEMENT, 2007, 48 (03) :937-941
[8]   Kinetics of the non-catalytic transesterification of soybean oil [J].
Diasakou, M ;
Louloudi, A ;
Papayannakos, N .
FUEL, 1998, 77 (12) :1297-1302
[9]   TRANSESTERIFICATION KINETICS OF SOYBEAN OIL [J].
FREEDMAN, B ;
BUTTERFIELD, RO ;
PRYDE, EH .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1986, 63 (10) :1375-1380
[10]   VARIABLES AFFECTING THE YIELDS OF FATTY ESTERS FROM TRANSESTERIFIED VEGETABLE-OILS [J].
FREEDMAN, B ;
PRYDE, EH ;
MOUNTS, TL .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 1984, 61 (10) :1638-1643