Polynitrile-bridged two-dimensional crystal: Eu(III) complex with strong fluorescence emission and NLO property

被引：78

作者：

Shi, JM ^{[1
]}

Xu, W

Liu, QY

Liu, FL

Huang, ZL

Lei, H

Yu, WT

Fang, Q

机构：

[1] Shandong Normal Univ, Dept Chem, Jinan 250014, Peoples R China

[2] Zhongshan Univ, Inst Laser & Spect, Guangzhou 510275, Peoples R China

[3] Shandong Univ, Inst Crystal Mat, Jinan 250010, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 07期

关键词：

D O I：

10.1039/b200894g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first polynitrile coordinated lanthanide complex {[Eu- (cda)(3)(H2O)(3)].H2O}infinity (cda = carbamyldicyanomethanide anion) has been synthesized and the two- dimensional structure coordination polymer exhibits strong fluorescence emission and strong powder second harmonic generation efficiency (16.8 times that of urea).

引用

页码：756 / 757

页数：2

共 10 条

[1] [(RE2CL4(DPPM)2)2(MU-TCNQ)], A NOVEL CHARGE-TRANSFER COMPLEX DERIVED FROM A DONOR WITH A METAL-METAL MULTIPLE BOND [J].

BARTLEY, SL ;

DUNBAR, KR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04) :448-450

[2] Signaling recognition events with fluorescent sensors and switches [J].

de Silva, AP ;

Gunaratne, HQN ;

Gunnlaugsson, T ;

Huxley, AJM ;

McCoy, CP ;

Rademacher, JT ;

Rice, TE .

CHEMICAL REVIEWS, 1997, 97 (05) :1515-1566

[3] Designer crystals: intermolecular interactions, network structures and supramolecular synthons [J].

Desiraju, GR .

CHEMICAL COMMUNICATIONS, 1997, (16) :1475-1482

[4] DCNQIS - NEW ELECTRON-ACCEPTORS FOR CHARGE-TRANSFER COMPLEXES AND HIGHLY CONDUCTING RADICAL-ANION SALTS [J].

HUNIG, S ;

ERK, P .

ADVANCED MATERIALS, 1991, 3 (05) :225-236

[5] THE COORDINATION CHEMISTRY OF TCNE, TCNQ AND RELATED POLYNITRILE PI-ACCEPTORS [J].

KAIM, W ;

MOSCHEROSCH, M .

COORDINATION CHEMISTRY REVIEWS, 1994, 129 (1-2) :157-193

[6] A POWDER TECHNIQUE FOR EVALUATION OF NONLINEAR OPTICAL MATERIALS [J].

KURTZ, SK ;

PERRY, TT .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1968, QE 4 (05) :333-+

[7] Light- and thermal-induced spin crossover in {Fe(abpt)2[N(CN)2]2}.: Synthesis, structure, magnetic properties, and high-spin ⇆ low-spin relaxation studies [J].

Moliner, N ;

Gaspar, AB ;

Muñoz, MC ;

Niel, V ;

Cano, J ;

Real, JA .

INORGANIC CHEMISTRY, 2001, 40 (16) :3986-3991

[8] Construction of copper(I) coordination polymers of 1,2,4,5-tetracyanobenzene with zigzag sheet and porous frameworks [J].

Munakata, M ;

Ning, GL ;

Kuroda-Sowa, T ;

Maekawa, M ;

Suenaga, Y ;

Horino, T .

INORGANIC CHEMISTRY, 1998, 37 (21) :5651-5656

[9]

SKOPENKO VV, 1981, UKR KHIM ZH+, V47, P1095

[10]

SKOPENKO VV, 1982, UKR KHIM ZH, V48, P106

← 1 →