Enantioselective syntheses of (+)- and (-)-phaseolinic acids

被引：42

作者：

Jacobi, PA

Herradura, P

机构：

[1] Hall-Atwater Laboratories, Wesleyan University, Middletown

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 46期

关键词：

D O I：

10.1016/0040-4039(96)01941-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(+)- and (-)-Phaseolinic acid (1) have been prepared in an enantioselective fashion from acetylenic acid 26 (or ent-26) by a three step sequence involving lactonization, epimerization at Cg, and oxidative cleavage. 26 was obtained as a single enantiomer using a Nicholas-Schreiber reaction. Copyright (C) 1996 Elsevier Science Ltd

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页码：8297 / 8300

页数：4

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