New fluorescent rhodamine hydrazone chemosensor for Cu(II) with high selectivity and sensitivity

被引：667

作者：

Xiang, Yu ^{[1
]}

Tong, Aijun ^{[1
]}

Jin, Peiyuan ^{[1
]}

Ju, Yong ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

ORGANIC LETTERS | 2006年 / 8卷 / 13期

关键词：

D O I：

10.1021/ol0610340

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new fluorescent probe, salicylaldehyde rhodamine B hydrazone (1), was synthesized and displayed selective Cu(II)-amplified absorbance and fluorescence emission above 500 nm in neutral buffered media. Upon the addition of Cu(II), the spirolactam ring of 1 was opened and a 1:1 metal-ligand complex was formed. The detection of Cu(II) by 1 at a lower micromolar level was successful even in buffered water.

引用

页码：2863 / 2866

页数：4

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