Pt and PtRh nanowire electrocatalysts for cyclohexane-fueled polymer electrolyte membrane fuel cell

被引：54

作者：

Kim, Hyung Ju ^{[1
]}

Kim, Yong Seok ^{[1
]}

Seo, Min Ho ^{[1
]}

Choi, Sung Mook ^{[1
]}

Kim, Won Bae ^{[1
]}

机构：

[1] GIST, Dept Mat Sci & Engn, Kwangju 500712, South Korea

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2009年 / 11卷 / 02期

关键词：

Electrospinning; Bimetallic nanowires; PtRh; Cyclohexane oxidation; Fuel cells; HYDROGEN;

D O I：

10.1016/j.elecom.2008.12.027

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical dehydrogenative oxidation of cyclohexane to benzene is studied over Pt and Pt1Rh1 nanowire electrocatalysts fabricated by electrospinning method, which shows the higher catalytic activities in a polymer electrolyte membrane fuel cell anode than the conventional Pt nanoparticle catalysts such as carbon-supported Pt or Pt black. The improved performances over the Pt1Rh1 nanowire electrocatalyst can be rationalized by enhanced electrical property and pertinent interface formation with nanowire catalysts in the high Pt-loaded cyclohexane fuel cell system. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：446 / 449

页数：4

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