Photoinduced alkyl group exchange of ethylzinc alkoxides:: X-ray crystal structure of an iodomethylzinc methoxide

被引：17

作者：

Charette, A

Beauchemin, A

Francoeur, S

Bélanger-Gariépy, F

Enright, GD

机构：

[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 05期

关键词：

D O I：

10.1039/b110736d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Irradiation of a solution of ethyl zinc alkoxides and CH2I2 leads to clean formation of iodomethylzinc alkoxides; these intermediates are important species generated in stereoselective cyclopropanation processes; no alkyl group exchange is observed in the absence of irradiation; the solid-state structure of (MeO)(8)Zn-7(CH2I)(6) is also reported.

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收藏

页码：466 / 467

页数：2

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