Infrared spectroscopic study of solid-state protonation and oxidation of polyaniline

被引：99

作者：

Trchová, M ^{[1
]}

Stejskal, J

Prokes, J

机构：

[1] Charles Univ, Fac Math & Phys, Prague 12116 2, Czech Republic

[2] Acad Sci Czech Republ, Inst Macromol Chem, CR-16206 Prague 6, Czech Republic

来源：

SYNTHETIC METALS | 1999年 / 101卷 / 1-3期

关键词：

infrared spectroscopy; polyaniline;

D O I：

10.1016/S0379-6779(98)01310-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Infrared spectrum of the polyaniline sulfate was compared with the spectrum of the polyaniline base after solid-state protonation with an equimolar amount of camphorsulfonic acid and with the spectrum of the polyaniline base after solid-state oxidation with ammonium peroxodisulfate. In both cases electrically conducting product was obtained, The bands characteristic of conducting protonated or oxidized form were identified in the spectra of the blends.

引用

页码：840 / 841

页数：2

共 6 条

[1] POLYANILINE ACID DOPANT INTERACTION IN THE PRESENCE OF 1-METHYL-2-PYRROLIDONE [J].

CHEN, SA ;

LEE, HT .

SYNTHETIC METALS, 1992, 47 (02) :233-238

[2] MASSIVE POLARONS IN LARGE-ENERGY-GAP POLYMERS [J].

MCCALL, RP ;

GINDER, JM ;

ROE, MG ;

ASTURIAS, GE ;

SCHERR, EM ;

MACDIARMID, AG ;

EPSTEIN, AJ .

PHYSICAL REVIEW B, 1989, 39 (14) :10174-10178

[3] Vibrational spectroscopic studies of the isotope effects in polyaniline [J].

Quillard, S ;

Louarn, G ;

Buisson, JP ;

Boyer, M ;

Lapkowski, M ;

Pron, A ;

Lefrant, S .

SYNTHETIC METALS, 1997, 84 (1-3) :805-806

[4] STRUCTURAL AND ELECTRONIC-TRANSITIONS IN POLYANILINE - A FOURIER-TRANSFORM INFRARED SPECTROSCOPIC STUDY [J].

SARICIFTCI, NS ;

KUZMANY, H ;

NEUGEBAUER, H ;

NECKEL, A .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (07) :4530-4539

[5] The formation of polyaniline and the nature of its structures [J].

Stejskal, J ;

Kratochvil, P ;

Jenkins, AD .

POLYMER, 1996, 37 (02) :367-369

[6] Solid-state protonation and electrical conductivity of polyaniline [J].

Stejskal, J ;

Sapurina, I ;

Trchova, M ;

Prokes, J ;

Krivka, I ;

Tobolkova, E .

MACROMOLECULES, 1998, 31 (07) :2218-2222

← 1 →