Catalytic asymmetric epoxidation of aliphatic enones using tartrate-derived magnesium alkoxides

被引：36

作者：

Jacques, O

Richards, SJ

Jackson, RFW

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 24期

关键词：

D O I：

10.1039/b109421a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Simple aliphatic enones can be converted into the corresponding epoxides in 71-93% ee using tert-butylhydroperoxide in the presence of a catalyst derived from dibutylmagnesium and di-tert-butyl tartrate.

引用

页码：2712 / 2713

页数：2

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