Densities, viscosities, and conductivities of mixtures of benzene with the Lewis acidic aluminum chloride plus 1-methyl-3-ethylimidazolium chloride molten salt

被引:52
作者
Liao, Q [1 ]
Hussey, CL [1 ]
机构
[1] UNIV MISSISSIPPI,DEPT CHEM,UNIVERSITY,MS 38677
关键词
D O I
10.1021/je960123s
中图分类号
O414.1 [热力学];
学科分类号
摘要
The densities, kinematic viscosities, and specific conductances of mixtures of benzene with the Lewis acidic room-temperature chloroaluminate molten salt aluminum chloride + 1-methyl-3-ethylimidazolium chloride (AlCl3 + MeEtimCl) were determined at 298.2 K. Benzene was added to melts containing 51.00, 60.00, and 66.67 mol % AlCl3. Simple polynomial equations were fitted to the experimental results as a function of the mass fraction of benzene. The addition of small amounts of benzene resulted in a decrease in the kinematic viscosity and an increase in the specific conductance of the mixture. However, the addition of benzene beyond 35 mass % caused the specific conductance to decrease due to a decrease in the concentration of charge-carrying ions.
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页码:1126 / 1130
页数:5
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