Study of Au(I)-polypyrrole interaction

被引：23

作者：

Rau, JR ^{[1
]}

Lee, JC ^{[1
]}

Chen, SC ^{[1
]}

机构：

[1] FU JEN CATHOLIC UNIV,DEPT CHEM,TAIPEI 242,TAIWAN

来源：

SYNTHETIC METALS | 1996年 / 79卷 / 01期

关键词：

polypyrrole; gold-polypyrrole complexation; cyclic voltammetry; sensors; cationic interference;

D O I：

10.1016/0379-6779(96)80133-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Metal-deposited polypyrrole (Ppy) exhibiting traits of enhanced conductivities and catalysis has aroused interest in the investigation of metal-Ppy interaction. Recently, a Ppy-based NOx- sensor was found to be interfered with by metal ions such as Ag(I), Cu(II) and Pb(II), hinting at a strong interaction between cations and Ppy. Au(I) was chosen for study because of its possible stronger affinity to Ppy. Results from NMR, cyclic voltammetry (CV) and a scanning electron microscopy (SEM)/energy-dispersive spectroscopy (EDS) study suggested the existence of the Au(I)-Ppy complex.

引用

页码：69 / 74

页数：6

共 13 条

[11] THE REDUCTION OF DIOXYGEN AT POLYPYRROLE-MODIFIED ELECTRODES WITH INCORPORATED PT PARTICLES [J].