MeO-biphep as an eight-electron donor to ruthenium(II). Chiral dialkyl complexes with an unprecedented binding mode

被引：18

作者：

Feiken, N ^{[1
]}

Pregosin, PS ^{[1
]}

Trabesinger, G ^{[1
]}

机构：

[1] ETH ZURICH,CH-8092 ZURICH,SWITZERLAND

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 17期

关键词：

D O I：

10.1021/om970323c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chiral bis(3,5-di-tert-butylphenyl)phosphino MeO-Biphep complex Ru(OAc)(2)(1a), with two complexed P donors, reacts with MeLi to give Ru(Me)(2)(1a), in which only one P atom is coordinated together with an arene eta(6)-C6H3 moiety derived from one of the biaryl rings. This is an unprecedented binding mode for this type of chiral complex.

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页码：3735 / 3736

页数：2

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