One-Dimensional Cyanide-Bridged MnIIIWV Bimetallic Complexes: Metamagnetism, Spontaneous Resolution, and Slow Magnetic Relaxation

被引：39

作者：

Choi, Seok Woo ^{[1
]}

Ryu, Dae Won ^{[1
]}

Lee, Jin Wuk ^{[1
]}

Yoon, Jung Hee ^{[1
]}

Kim, Hyoung Chan ^{[2
]}

Lee, Hyosug ^{[3
]}

Cho, Beong Ki ^{[4
]}

Hong, Chang Seop ^{[1
]}

机构：

[1] Korea Univ, Dept Chem BK21, Seoul 136713, South Korea

[2] Natl Fus Res Inst, Taejon 305333, South Korea

[3] SAIT, Mat Res Lab, Hybrid Mat Grp, Yongin 446712, South Korea

[4] GIST, Dept Mat Sci & Engn, Kwangju 500712, South Korea

来源：

INORGANIC CHEMISTRY | 2009年 / 48卷 / 19期

关键词：

SINGLE-CHAIN MAGNET; WEAK FERROMAGNETISM; CHIRAL DICHROISM; T-C; MOLECULE; FERRIMAGNET; TRANSITION; MN; NI;

D O I：

10.1021/ic901610j

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学];

摘要：

The reaction of [W(CN)(6)(bpy)](-) with the corresponding Mn Schiff bases led to the formation of two antiferromagnetic (1) and ferromagnetic (2) chains. The formation of the conglomerate (2) is associated with chiral induction by the enantiomeric chelate-ring conformation of the Mn Schiff base. Modulation of the linking groups in the Mn Schiff bases affects the interchain contacts, causing alteration of the magnetic behaviors from metamagnetism (1) to slow magnetic relaxation (2).

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收藏

页码：9066 / 9068

页数：3

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