Study of the enantiomeric composition of chiral constituents in edible oils by simultaneous distillation-extraction. Detection of adulterated olive oils

被引:12
作者
Caja, MM [1 ]
del Castillo, MLR [1 ]
Herraiz, M [1 ]
Blanch, GP [1 ]
机构
[1] CSIC, Inst Fermentac Ind, E-28006 Madrid, Spain
关键词
adulteration; enantiomeric composition; filbertone; hazelnut oil; olive oil;
D O I
10.1007/s11746-999-0200-6
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A method is proposed for detecting adulterations of olive oil with hazelnut oil at percentages as low as 5%. The method is based on the identification of R- and S-enantiomers of E-5-methylhept-2-en-4-one (filbertone) and involves the use of simultaneous distillation-solvent extraction in the sample preparation step and subsequent gas chromatographic analysis with a chiral stationary phase. Relative standard deviation values obtained from three replicates of adulterated mixtures of olive oil and hazelnut oil (95:5) were less than 9% for both R- and S-filbertone.
引用
收藏
页码:1027 / 1030
页数:4
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