X-ray structure and theoretical studies of RuH2(η2,H2)(η2-H-SiPh3)(PCy3)2, a complex with two different η2-coordinated σ bonds

被引:60
作者
Hussein, K
Marsden, CJ
Barthelat, JC
Rodriguez, V
Conejero, S
Sabo-Etienne, S
Donnadieu, B
Chaudret, B
机构
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 04, France
[2] Univ Toulouse 3, IRSAMC, Phys Quant Lab, UMR 5626, F-31062 Toulouse, France
[3] Univ Al Baath, Fac Sci, Dept Chem, Homs, Syria
关键词
D O I
10.1039/a901558b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Weak interactions between the silicon and the hydrides are responsible for the stabilization of the title complex bearing two different coordinated sigma-bonds, (eta(2)-H-2) and (eta(2)-H-SiPh3).
引用
收藏
页码:1315 / 1316
页数:2
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