On the palladium(II)-catalysed oxidative rearrangement of propargylic acetates

被引：17

作者：

Bartels, A ^{[1
]}

Mahrwald, R ^{[1
]}

Müller, K ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2004年 / 346卷 / 04期

关键词：

oxidation; palladium; rearrangement;

D O I：

10.1002/adsc.200303200

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The catalytic transformation of propargylic acetates into the corresponding alpha-acetoxyenones in the presence of palladium(II) chloride is described. Water is a necessary component in this unusual oxidative rearrangement.

引用

页码：483 / 485

页数：3

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