Facile synthesis of novel functionalized bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF) derivatives

被引:69
作者
Liu, SX [1 ]
Dolder, S [1 ]
Pilkington, M [1 ]
Decurtins, S [1 ]
机构
[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland
关键词
D O I
10.1021/jo0163694
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An improved and efficient synthetic route to four functionalized bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) derivatives 2-5 is reported. Tetrathiolate 1 was readily prepared from 2,2'-bis (1,3,4,6-tetrathiapentalen-5-one) under carefully controlled conditions. Subsequent reaction of 1 with selected primary alkyl halides affords new functionalized BEDT-TTF derivatives in good yields.
引用
收藏
页码:3160 / 3162
页数:3
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