Recent uses of iron (III) chloride in organic synthesis

被引：135

作者：

Díaz, DD ^{[1
]}

Miranda, PO ^{[1
]}

Padrón, JI ^{[1
]}

Martín, VS ^{[1
]}

机构：

[1] Univ La Laguna, Inst Univ Bioorgan Antonio Gonzalez, E-38206 Tenerife, Spain

来源：

CURRENT ORGANIC CHEMISTRY | 2006年 / 10卷 / 04期

关键词：

D O I：

10.2174/138527206776055330

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iron (III) chloride is extensively used in organic synthesis as an ideal Lewis acid since it is an inexpensive, efficient, stable, environmentally friendly and a convenient agent for several useful reactions Such as; polymerisations, oxidations, oxidative Couplings, reductions, C-C bond formation, Ferrier rearrangement, one-pot multicomponent condensations, Friedel-Crafts reactions, cyclisations, glycosidation, Prins-type cyclisation, deprotection of various functional groups, and as a reagent in key steps of natural products synthesis. This comprehensive review attempts to cover the advances in this field, which have occurred in the last five years.

引用

页码：457 / 476

页数：20

共 146 条

[1]

Amou S, 1999, J POLYM SCI POL CHEM, V37, P1943, DOI 10.1002/(SICI)1099-0518(19990701)37:13<1943::AID-POLA7>3.0.CO

[2]

2-X

[3] Synthesis of regioregular phenyl substituted polythiophenes with FeCl3 [J].

Andersson, MR ;

Mammo, W ;

Olinga, T ;

Svensson, M ;

Theander, M ;

Inganäs, O .

SYNTHETIC METALS, 1999, 101 (1-3) :11-12

[4] Iron(III) chloride as a water-compatible Lewis acid for diastereoselective aldol reactions in water in the presence of a surfactant [J].

Aoyama, N ;

Manabe, K ;

Kobayashi, S .

CHEMISTRY LETTERS, 2004, 33 (03) :312-313

[5] Friedel-Crafts acylation of toluene catalyzed by solid superacids [J].

Arata, K ;

Nakamura, H ;

Shouji, M .

APPLIED CATALYSIS A-GENERAL, 2000, 197 (02) :213-219

[6] An efficient one-pot synthesis of aromatic nitriles from aldehydes using Fe modified K10. [J].

Bajpai, AR ;

Deshpande, AB ;

Samant, SD .

SYNTHETIC COMMUNICATIONS, 2000, 30 (15) :2785-2791

[7] STANNIC TETRACHLORIDE CATALYZED GLYCOSYLATION OF 8-ETHOXYCARBONYLOCTANOL BY CELLOBIOSE, LACTOSE, AND MALTOSE OCTAACETATES - SYNTHESIS OF ALPHA-GLYCOSIDIC AND BETA-GLYCOSIDIC LINKAGES [J].

BANOUB, J ;

BUNDLE, DR .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1979, 57 (16) :2085-2090

[8]

Barrett IC, 2000, SYNLETT, P1673

[9] Facile preparation of hydrazones by the treatment of azides with hydrazines catalyzed by FeCl3•6H2O [J].

Barrett, IC ;

Langille, JD ;

Kerr, MA .

JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (19) :6268-6269

[10] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

← 1 2 3 4 5 6 7 8 9 10 →