Recent uses of iron (III) chloride in organic synthesis

被引:135
作者
Díaz, DD [1 ]
Miranda, PO [1 ]
Padrón, JI [1 ]
Martín, VS [1 ]
机构
[1] Univ La Laguna, Inst Univ Bioorgan Antonio Gonzalez, E-38206 Tenerife, Spain
关键词
D O I
10.2174/138527206776055330
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Iron (III) chloride is extensively used in organic synthesis as an ideal Lewis acid since it is an inexpensive, efficient, stable, environmentally friendly and a convenient agent for several useful reactions Such as; polymerisations, oxidations, oxidative Couplings, reductions, C-C bond formation, Ferrier rearrangement, one-pot multicomponent condensations, Friedel-Crafts reactions, cyclisations, glycosidation, Prins-type cyclisation, deprotection of various functional groups, and as a reagent in key steps of natural products synthesis. This comprehensive review attempts to cover the advances in this field, which have occurred in the last five years.
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收藏
页码:457 / 476
页数:20
相关论文
共 146 条
[61]   A novel one-pot synthesis of cyanohydrin alkyl ethers from aldehydes catalyzed by iron(III) chloride [J].
Iwanami, K ;
Oriyama, T .
CHEMISTRY LETTERS, 2004, 33 (10) :1324-1325
[62]  
Jain SK, 2000, ASIAN J CHEM, V12, P1341
[63]   FeCl3-NaI mediated reactions of aryl azides with 3,4-dihydro-2H-pyran:: a convenient synthesis of pyranoquinolines [J].
Kamal, A ;
Prasad, BR ;
Ramana, AV ;
Babu, AH ;
Reddy, KS .
TETRAHEDRON LETTERS, 2004, 45 (17) :3507-3509
[64]  
Kamal A, 2000, SYNLETT, P1476
[65]   A new method for the synthesis of N-benzylamides [J].
Karabulut, HRF ;
Kacan, M .
SYNTHETIC COMMUNICATIONS, 2002, 32 (15) :2345-2348
[66]   Studies in Beckmann rearrangement of substituted benzophenone and acetophenone oximes [J].
Khadilkar, BM ;
Upadhyaya, DJ .
SYNTHETIC COMMUNICATIONS, 2002, 32 (12) :1867-1873
[67]   Simple preparations of alkyl and cycloalkyl α-glycosides of maltose, cellobiose, and lactose [J].
Koto, S ;
Hirooka, M ;
Tashiro, T ;
Sakashita, M ;
Hatachi, M ;
Kono, T ;
Shimizu, M ;
Yoshida, N ;
Kurasawa, S ;
Sakuma, N ;
Sawazaki, S ;
Takeuchi, A ;
Shoya, N ;
Nakamura, E .
CARBOHYDRATE RESEARCH, 2004, 339 (14) :2415-2424
[68]   ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM [J].
KRESGE, CT ;
LEONOWICZ, ME ;
ROTH, WJ ;
VARTULI, JC ;
BECK, JS .
NATURE, 1992, 359 (6397) :710-712
[69]   Highly deoxygenated sugars.: I.: C2-branched glucose derivatives and carbon linked deoxygenated disaccharides [J].
Krohn, K ;
Flörke, U ;
Gehle, D .
JOURNAL OF CARBOHYDRATE CHEMISTRY, 2002, 21 (05) :431-443
[70]   An efficient oxidation of 2-aryl-1,2,3,4-tetrahydro-4-quinolones employing ferric chloride hexahydrate-methanol: synthesis of naturally occurring 4-alkoxy-2-arylquinolines [J].
Kumar, KH ;
Muralidharan, D ;
Perumal, PT .
TETRAHEDRON LETTERS, 2004, 45 (42) :7903-7906