Self-Healing Polymer Coatings Based on Crosslinked Metallosupramolecular Copolymers

被引：389

作者：

Bode, Stefan ^{[1
,2
]}

Zedler, Linda ^{[2
,3
,4
,5
]}

Schacher, Felix H. ^{[1
,2
]}

Dietzek, Benjamin ^{[2
,3
,4
,5
]}

Schmitt, Michael ^{[2
,3
,4
]}

Popp, Juergen ^{[2
,3
,4
,5
]}

Hager, Martin D. ^{[1
,2
]}

Schubert, Ulrich S. ^{[1
,2
,6
]}

机构：

[1] Univ Jena, Lab Organ & Macromol Chem IOMC, D-07743 Jena, Germany

[2] Univ Jena, JCSM, D-07743 Jena, Germany

[3] Univ Jena, IPC, D-07743 Jena, Germany

[4] Univ Jena, ACP, D-07743 Jena, Germany

[5] Inst Photon Technol IPHT Jena, D-07745 Jena, Germany

[6] DPI, NL-5600 AX Eindhoven, Netherlands

来源：

ADVANCED MATERIALS | 2013年 / 25卷 / 11期

关键词：

self-healing materials; self-healing polymers; metallopolymers; polymer coatings; ELASTIC-MODULUS; INDENTATION; TERPYRIDINE; TRANSITION; COMPLEXES; HARDNESS; LOAD;

D O I：

10.1002/adma.201203865

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Self-healing coating based on metallopolymers are prepared and fully characterized. Iron bisterpyridine complexes are incorporated into a polymer network based on methacrylates, resulting in self-healing properties of these materials. Moreover, the influence of the comonomers on the thermal properties is studied in detail.

引用

页码：1634 / 1638

页数：5

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