Radiolytic reduction of Ag(CN)(2)(-) solution: Ligand effect on the redox potential

被引：12

作者：

Texier, I ^{[1
]}

Mostafavi, M ^{[1
]}

机构：

[1] UNIV PARIS 11,LAB PHYSICOCHIM RAYONNEMENTS,CNRS URA 75,CTR ORSAY,F-91405 ORSAY,FRANCE

来源：

RADIATION PHYSICS AND CHEMISTRY | 1997年 / 49卷 / 04期

关键词：

D O I：

10.1016/S0969-806X(96)00172-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

gamma-irradiation and pulse radiolysis are used to check experimentally the ligand effect of the redox potential of the cyano-silver monomer couple Ag-1(CN)(2)(-)/Ag-0(CN)(2)(2-) found to be lower than -2.1 V-NHE instead of equal to -2.6 V-NHE as in a previous theoretical evaluation (Remita et al., 1995, Journal of Physical Chemistry 99, 13198). We present a mechanism explaining the reduction of Ag(CN)(2)(-) by the radical anion (CH3)(2)CO- indicating that the redox potential of the couple [2Ag(1)(CN)(2)(-)/Ag-2(+), xCN(-)] lies between -2.1 and -1.7 V-NHE Copyright (C) 1997 Elsevier Science Ltd.

引用

页码：459 / 464

页数：6

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