Synthesis of [Au3Fe2(CO)(8)(dppm)](-) and [Au5Fe2(CO)(8)(dppm)(2)](+): X-ray structures of [NEt(4)][Au3Fe2(CO)(8)(dppm)] and [Au5Fe2(CO)(8)(dppm)(2)][BF4]

被引：14

作者：

Albano, VG

Iapalucci, MC

Longoni, G

Manzi, L

Monari, M

机构：

[1] UNIV BOLOGNA,DIPARTIMENTO CHIM FIS & INORGAN,I-40136 BOLOGNA,ITALY

[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 04期

关键词：

D O I：

10.1021/om960850g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The [Au3Fe2(CO)(8)(dppm)](-) cluster anion has been isolated from the reaction of either [AuFe2(CO)(8)](3-) or [Fe(CO)(4)](2-) with Au-2(dppm)Cl-2 in THF, whereas the [Au5Fe2(CO)(8)(dppm)(2)](+) cluster cation has been obtained by oxidation of the former; both new compounds have been characterized by X-ray studies on their [NEt(4)][Au-3-Fe-2(CO)(8)(dppm)] and [Au5Fe2(CO)(8)(dppm)2][BF4] salts, respectively.

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页码：497 / 499

页数：3

相关论文

共 16 条

[1] STRUCTURAL CHARACTERIZATION OF THE TRINUCLEAR CLUSTER COMPOUND [FE(CO)(4)(AUPPH(3))(2)] AND ISOLATION OF ITS PARENT ANION [FE(CO)(4)(AUPPH(3))](-) [J].

ALBANO, VG ;

MONARI, M ;

IAPALUCCI, MC ;

LONGONI, G .

INORGANICA CHIMICA ACTA, 1993, 213 (1-2) :183-190

[2] SYNTHESIS OF [AUFE2(CO)(8)](3-) AND [AU4FE4(CO)(16)](4-) - X-RAY STRUCTURE OF THE [AU4FE4(CO)(16)](4-) CLUSTER ANION IN ITS [NET(4)](+) SALT [J].

ALBANO, VG ;

CALDERONI, F ;

IAPALUCCI, MC ;

LONGONI, G ;

MONARI, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (04) :433-434

[3] SYNTHESIS, CHEMICAL CHARACTERIZATION, AND BONDING ANALYSIS OF THE [AG(FE(CO)(4))(2)](3-), [AG-4(MU(2)-FE(CO)(4))(4)](4-), AND [AG-5(MU(2)-FE(CO)(4))(2)(MU(3)-FE(CO)(4))(2)](3-) CLUSTER ANIONS - X-RAY STRUCTURAL DETERMINATION OF [NME(3)CH(2)PH](4)[AG4FE4(CO16)] AND [NET(4)](3)[AG5FE4(CO)(16)] [J].

ALBANO, VG ;

AZZARONI, F ;

IAPALUCCI, MC ;

LONGONI, G ;

MONARI, M ;

MULLEY, S ;

PROSERPIO, DM ;

SIRONI, A .

INORGANIC CHEMISTRY, 1994, 33 (23) :5320-5328

[4] SQUARE FE2AU2 AND TRIANGULAR FE2AU CLUSTERS - A REVERSIBLE TRANSFORMATION - X-RAY CRYSTAL-STRUCTURE OF [FE2AU2(CO)8(MU-DPPM)] (DPPM = BIS(DIPHENYLPHOSPHINO)METHANE) [J].

ALVAREZ, S ;

ROSSELL, O ;

SECO, M ;

VALLS, J ;

PELLINGHELLI, MA ;

TIRIPICCHIO, A .

ORGANOMETALLICS, 1991, 10 (07) :2309-2314

[5] STRUCTURAL STUDIES ON MIXED IRON GOLD CLUSTERS WITH BIDENTATE TERTIARY PHOSPHINE-LIGANDS [J].

BRIANT, CE ;

HALL, KP ;

MINGOS, DMP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (15) :843-845

[6] MIXED COPPER IRON CLUSTERS - THE PREPARATION AND STRUCTURE OF THE LARGE PLANAR CLUSTER ANIONS, CU3FE3(CO)12(3-) AND CU5FE4(CO)16(3-) [J].

DOYLE, G ;

ERIKSEN, KA ;

VANENGEN, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (03) :445-451

[7] MIXED COPPER IRON CLUSTERS - THE PREPARATION AND STRUCTURES OF [(PH3P)2CU]2FE(CO)4 AND [(DIPHOS)2CU]2CU6FE4(CO)16 [J].

DOYLE, G ;

ERIKSEN, KA ;

VANENGEN, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (26) :7914-7920

[8] PREPARATION AND STRUCTURAL CHARACTERIZATION OF [AG2(DPM)2(NO3)2] AND [AG4(DPM)4(NO3)2]2+[PF6]-2 - CONFORMATIONAL FLEXIBILITY IN THE M2P4 CORE STRUCTURE OF BIS(DIPHENYLPHOSPHINO)METHANE COMPLEXES [J].

HO, DM ;

BAU, R .

INORGANIC CHEMISTRY, 1983, 22 (26) :4073-4079

[9] BUILDING BRIDGES BETWEEN INORGANIC AND ORGANIC-CHEMISTRY (NOBEL LECTURE) [J].

HOFFMANN, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (10) :711-724

[10] THE MONOCLINIC PHASE [AU2(C25H22P2)2]CL2.2CH3CN [J].

LIOU, LS ;

LIU, CP ;

WANG, JC .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1994, 50 :538-540