A novel synthesis of trifluoromethyl ethers via xanthates, utilizing BrF3

被引：50

作者：

Ben-David, I ^{[1
]}

Rechavi, D ^{[1
]}

Mishani, E ^{[1
]}

Rozen, S ^{[1
]}

机构：

[1] Tel Aviv Univ, Sch Chem, Raymond & Beverly Sackler Fac Exact Sci, IL-69978 Tel Aviv, Israel

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1999年 / 97卷 / 1-2期

关键词：

bromine trifluoride; trifluoromethyl ethers; alcohols to trifluoromethoxy;

D O I：

10.1016/S0022-1139(99)00031-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Alcohols were transformed into trifluoromethyl ethers by converting them to xanthates in almost quantitative yields followed by a reaction with bromine trifluoride, a reagent rarely used in organic chemistry. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：75 / 78

页数：4

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