Bifunctional Magneto-Optical FePt-CdS Hybrid Nanoparticles

被引:59
作者
He, Shuli [1 ,3 ]
Zhang, Hongwang [2 ]
Delikanli, Savas [1 ]
Qin, Yueling [1 ]
Swihart, Mark T. [2 ]
Zeng, Hao [1 ]
机构
[1] SUNY Buffalo, Dept Phys, Buffalo, NY 14260 USA
[2] SUNY Buffalo, Dept Chem & Biol Engn, Buffalo, NY 14260 USA
[3] Capital Normal Univ, Dept Phys, Beijing 100037, Peoples R China
基金
美国国家科学基金会;
关键词
CDSE/CDS CORE/SHELL NANOCRYSTALS; ONE-POT SYNTHESIS; MAGNETIC NANOPARTICLES; SELECTIVE GROWTH; QUANTUM DOTS; SEMICONDUCTOR; HETEROSTRUCTURES; NANOSTRUCTURES; NANOCOMPOSITES; PERSPECTIVES;
D O I
10.1021/jp806247f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper describes preparation of binary FePt-CdS hybrid nanoparticles by spontaneous heteroepitaxial nucleation and growth of the CdS component onto FePt-seed nanoparticles in high-temperature organic solution. FePt nanoparticles with average sizes of 4 and 9 nm were used as seeds. Lattice mismatch makes complete coating of the seed particles unfavorable, resulting in peanut-like and flower-like FePt-CdS nanoparticles. The CdS photoluminescence is quenched in 9 nm FePt-CdS hybrid nanoparticles. The band edge emission is observed in 4 nm FePt-CdS nanoparticles, albeit with substantially lower intensity than in pure US nanoparticles. We suggest that the strong FePt-size dependent photoluminescence intensity results from the interplay between interface charge transfer and quantum confinement effects.
引用
收藏
页码:87 / 90
页数:4
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