Thermal degradation of polyvinyl chloride

被引：25

作者：

Petre, AL

Budrugeac, P

Segal, E

机构：

[1] Romanian Acad, IG Murgulescu Inst Phys Chem, Bucharest 77208, Romania

[2] EUROTEST SA, Bucharest 73204, Romania

[3] Univ Bucharest, Fac Chem, Dept Phys Chem, Bucharest, Romania

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1999年 / 56卷 / 03期

关键词：

non-isothermal kinetic parameters; polyvinyl chloride; thermal degradation;

D O I：

10.1023/A:1010136507843

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The thermal degradation of a sort of polyvinyl chloride was investigated. Complex processes for polyvinyl chloride degradation were evidenced. The kinetic analysis of dehydrochlorination and of subsequent processes was carried out. A change of mechanism was detected when dehydrochlorination goes to completion. The values of non-isothermal kinetic parameters determined by various methods are in a satisfactory agreement. The obtained results allowed some clarifications concerning the thermal degradation steps.

引用

页码：1065 / 1070

页数：6

共 15 条

[1] DEGRADATION AND STABILIZATION OF POLY(VINYL CHLORIDE) .5. REACTION-MECHANISM OF POLY(VINYL CHLORIDE) DEGRADATION [J].