Approaching supramolecular functionality

被引:162
作者
Schalley, CA
Lützen, A
Albrecht, M
机构
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
[2] Carl von Ossietzky Univ Oldenburg, Fachbereich Chem, D-26111 Oldenburg, Germany
[3] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany
关键词
conformational control; molecular devices; self-assembly; supramolecular; chemistry; template effects;
D O I
10.1002/chem.200305150
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Functional molecules require a high degree of complexity which is difficult to achieve by covalent synthesis. This article discusses supramolecular approaches to the creation of larger architectures through non-covalent bonds, self-assembly, and template strategies. It highlights selected examples for the structural and conformational control of function and attempts to identify difficulties and challenges which may arise in future.
引用
收藏
页码:1072 / 1080
页数:9
相关论文
共 115 条
[1]  
Affeld A, 2001, EUR J ORG CHEM, V2001, P2877
[2]  
Albrecht M, 2000, CHEM-EUR J, V6, P3485, DOI 10.1002/1521-3765(20001002)6:19<3485::AID-CHEM3485>3.0.CO
[3]  
2-3
[4]   Mimicking the biologically active part of the cyclopeptides segetalin A and B by "clipping" of a linear tripeptide derivative by metal coordination [J].
Albrecht, M ;
Stortz, P ;
Weis, P .
SUPRAMOLECULAR CHEMISTRY, 2003, 15 (7-8) :477-483
[5]  
Albrecht M, 2003, SYNTHESIS-STUTTGART, P1105
[6]   Facile solid-phase synthesis of the WAGV-tetrapeptide front of the cyclopeptides segetalin A and B terminated by catechol moieties and formation of a metalla-cyclopeptide [J].
Albrecht, M ;
Stortz, P ;
Weis, P .
SYNLETT, 2003, (06) :867-869
[7]   Size-selectivity in the template-directed assembly of dinuclear triple-stranded helicates [J].
Albrecht, M ;
Blau, O ;
Fröhlich, R .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4867-4872
[8]   FORMATION OF A MESO-HELICATE BY SELF-ASSEMBLY OF 3 BIS(CATECHOLATE) LIGANDS AND 2 TITANIUM(IV) IONS [J].
ALBRECHT, M ;
KOTILA, S .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (19) :2134-2137
[9]  
Albrecht M, 1999, CHEM-EUR J, V5, P48, DOI 10.1002/(SICI)1521-3765(19990104)5:1<48::AID-CHEM48>3.3.CO
[10]  
2-Z