Synthesis of (E)- and (Z)-1-H-difluoromethanimine

被引：1

作者：

Bauknight, CW ^{[1
]}

DesMarteau, DD ^{[1
]}

机构：

[1] CLEMSON UNIV,DEPT CHEM,CLEMSON,SC 29634

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 06期

关键词：

D O I：

10.1021/ic951149s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel imine (E)-1-H-difluoromethanimine (1) is formed by reaction of CF2=NF with triphenylphosphine, followed by reaction with H2O. 1 is formed via an intermediate phosphorane (3). Acids catalyze the isomerization of 1 to the Z-isomer (2).

引用

页码：1417 / &

页数：3

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