Different CuO Nanostructures: Synthesis, Characterization, and Applications for Glucose Sensors

被引:226
作者
Zhang, Xiaojun [1 ,2 ]
Wang, Guangfeng [1 ,3 ]
Liu, Xiaowang [1 ,2 ]
Wu, Jingjing [1 ]
Li, Ming [1 ]
Gu, Jing [1 ]
Liu, Huan [1 ]
Fang, Bin [1 ,3 ]
机构
[1] Anhui Normal Univ, Coll Chem & Mat Sci, Wuhu 241000, Peoples R China
[2] Anhui Normal Univ, Anhui Key Lab Funct Mol Solids, Wuhu 241000, Peoples R China
[3] Anhui Normal Univ, Anhui Key Lab Chem Biosensing, Wuhu 241000, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1021/jp806985k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three different nanostructures of CuO (wires, platelets, and spindles) have been synthesized by one precursor. First, Cu(OH)(2) nanowires have been prepared by a two-step, template-free, wet chemical approach. And then the transformation from the 1D Cu(OH)(2) nanostructures to a variety of novel CuO nanostructures has been realized by thermal dehydration of the as-prepared Cu(OH)(2) in solution. The electrochemical characters of the three different nanostructures are studied by their investigation of electrochemical impendance spectrum and cyclic voltammetry. A comparison of the three nanostructures showed us an attractive phenomenon, that is, the electron transfer ability of CuO nanospindles was stronger than that of CuO nanowires or nanoplatelets. We suggest the possible reason is the assembly of the nanostructrue. The electrochemical response of the as-prepared samples on H2O2 is also investigated, and good application in electrochemical detecting of glucose is exhibited.
引用
收藏
页码:16845 / 16849
页数:5
相关论文
共 58 条
[1]   Shape-controlled synthesis of colloidal platinum nanoparticles [J].
Ahmadi, TS ;
Wang, ZL ;
Green, TC ;
Henglein, A ;
ElSayed, MA .
SCIENCE, 1996, 272 (5270) :1924-1926
[2]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[3]   Semiconductor nanocrystals as fluorescent biological labels [J].
Bruchez, M ;
Moronne, M ;
Gin, P ;
Weiss, S ;
Alivisatos, AP .
SCIENCE, 1998, 281 (5385) :2013-2016
[4]   Chemical approaches to semiconductor nanocrystals [J].
Brus, L .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1998, 59 (04) :459-465
[5]   Chemistry and properties of nanocrystals of different shapes [J].
Burda, C ;
Chen, XB ;
Narayanan, R ;
El-Sayed, MA .
CHEMICAL REVIEWS, 2005, 105 (04) :1025-1102
[6]   A controllable synthetic route to Cu, Cu2O, and CuO nanotubes and nanorods [J].
Cao, MH ;
Hu, CW ;
Wang, YH ;
Guo, YH ;
Guo, CX ;
Wang, EB .
CHEMICAL COMMUNICATIONS, 2003, (15) :1884-1885
[7]   Large-scale synthesis of high-quality ultralong copper nanowires [J].
Chang, Y ;
Lye, ML ;
Zeng, HC .
LANGMUIR, 2005, 21 (09) :3746-3748
[8]   ULTRAVIOLET VISIBLE ABSORPTION-SPECTRA OF THE COLLOIDAL METALLIC ELEMENTS [J].
CREIGHTON, JA ;
EADON, DG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1991, 87 (24) :3881-3891
[9]   The transformation of Cu(OH)2 into CuO, revisited [J].
Cudennec, Y ;
Lecerf, A .
SOLID STATE SCIENCES, 2003, 5 (11-12) :1471-1474
[10]   Functional nanoscale electronic devices assembled using silicon nanowire building blocks [J].
Cui, Y ;
Lieber, CM .
SCIENCE, 2001, 291 (5505) :851-853