Stoichiometric aerobic PtII-Me bond cleavage in aqueous solutions to produce methanol and a PtII(OH) complex

被引：94

作者：

Vedernikov, AN ^{[1
]}

Binfield, SA ^{[1
]}

Zavalij, PY ^{[1
]}

Khusnutdinova, JR ^{[1
]}

机构：

[1] Univ Maryland, Dept Chem & Biochem, College Pk, MD 20742 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 01期

关键词：

D O I：

10.1021/ja0575171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Di(2-pyridyl)methanesulfonate ligand allows for facile aerobic oxidation of a PtIIMe complex into PtIVMe(OH)2 species and clean C-O reductive elimination of methanol from the latter in either acidic or basic aqueous solutions. Copyright © 2006 American Chemical Society.

引用

页码：82 / 83

页数：2

共 24 条

[11] Platinum catalysts for the high-yield oxidation of methane to a methanol derivative
Periana, RA
Taube, DJ
Gamble, S
Taube, H
Satoh, T
Fujii, H
[J]. SCIENCE, 1998, 280 (5363) : 560 - 564
[12] Platinum(IV) hydride chemistry
Puddephatt, RJ
[J]. COORDINATION CHEMISTRY REVIEWS, 2001, 219 : 157 - 185
[13] Oxidation of dimethylplatinum(II) complexes with dioxygen
Rostovtsev, VV
Labinger, JA
Bercaw, JE
Lasseter, TL
Goldberg, KI
[J]. ORGANOMETALLICS, 1998, 17 (21) : 4530 - 4531
[14] Structural and mechanistic investigations of the oxidation of dimethylplatinum(II) complexes by dioxygen
Rostovtsev, VV
Henling, LM
Labinger, JA
Bercaw, JE
[J]. INORGANIC CHEMISTRY, 2002, 41 (14) : 3608 - 3619
[15] Scollard JD, 2001, HELV CHIM ACTA, V84, P3247, DOI 10.1002/1522-2675(20011017)84:10<3247::AID-HLCA3247>3.3.CO
[16] 2-N
[17] Activation of C-H bonds by metal complexes
Shilov, AE
Shul'pin, GB
[J]. CHEMICAL REVIEWS, 1997, 97 (08) : 2879 - 2932
[18] SHILOV AE, 2000, ACTICATION CATALYTIC
[19] Stahl SS, 1998, ANGEW CHEM INT EDIT, V37, P2181, DOI 10.1002/(SICI)1521-3773(19980904)37:16<2180::AID-ANIE2180>3.0.CO
[20] 2-A

← 1 2 3 →