Labeling interacting configurations through an analysis of excitation dynamics in a resonant photoemission experiment: the case of rutile TiO2

被引：13

作者：

Drera, G. ^{[1
,2
]}

Sangaletti, L. ^{[1
,2
]}

Bondino, F. ^{[3
]}

Malvestuto, M. ^{[4
]}

Malavasi, L. ^{[5
]}

Diaz-Fernandez, Y. ^{[5
]}

Dash, S. ^{[1
,2
]}

Mozzati, M. C. ^{[6
,7
]}

Galinetto, P. ^{[6
,7
]}

机构：

[1] Univ Cattolica, I LAMP, I-25121 Brescia, Italy

[2] Univ Cattolica, Dipartimento Matemat & Fis, I-25121 Brescia, Italy

[3] IOM CNR, Lab TASC, I-34149 Basovizza, Italy

[4] Sincrotrone Trieste, I-34149 Basovizza, Italy

[5] Univ Pavia, Dipartimento Chim, I-27100 Pavia, Italy

[6] Univ Pavia, CNISM, I-27100 Pavia, Italy

[7] Univ Pavia, Dipartimento Fis, I-27100 Pavia, Italy

来源：

JOURNAL OF PHYSICS-CONDENSED MATTER | 2013年 / 25卷 / 07期

关键词：

CHARGE-TRANSFER; 2P; METAL; SURFACE; EDGES;

D O I：

10.1088/0953-8984/25/7/075502

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

A detailed study of resonant photoemission at Ti L-2,L-3 edges of insulating rutile TiO2-x thin film is presented. Pure TiO2 resonating structures, defect-related resonances, resonant Raman-Auger and normal LVV Auger emissions are tracked, including an unpredicted two-hole correlated satellite below the non-bonding part of the valence band. The analysis of excitation dynamics unambiguously addresses the origin of these features and, in particular, the extent of charge transfer effects on the Ti-O bonding in the valence band of rutile, disclosing further applications to the more general case of, formally, d(0) oxides.

引用

页数：7

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