Structure-inheriting solid-state reactions under hydrothermal conditions

被引：31

作者：

Eda, K ^{[1
]}

Uno, Y

Nagai, N

Sotani, N

Chen, C

Whittingham, MS

机构：

[1] Kobe Univ, Fac Sci, Dept Chem, Nada Ku, Kobe, Hyogo 6578501, Japan

[2] SUNY Binghamton, Inst Mat Res, Binghamton, NY 13902 USA

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2006年 / 179卷 / 05期

基金：

美国国家科学基金会;

关键词：

hydrothermal synthesis; solid-state reaction; soft chemistry; cobalt molybdate;

D O I：

10.1016/j.jssc.2006.01.060

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have explored several structure inheriting, solid-state reactions (SISSRS) under hydrothermal conditions for syntheses in the Co-Mo-O system. And we found an interesting hydrothermal SISSR CoMoO4 center dot 3/4H(2)O to high-pressure (hp-) phase of CoMoO4(,) which enabled us to considerably reduce the severe conditions for the synthesis of hp-CoMoO4. As similar hydrothermal SISSRs are expected to be useful tools for material syntheses, we also briefly discuss them as a means of developing, novel material Syntheses and designs. (C) 2006 Elsevier Inc. All rights reserved.

引用

页码：1453 / 1458

页数：6

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