Quaternary Nanocomposites Consisting of Graphene, Fe3O4@Fe Core@Shell, and ZnO Nanoparticles: Synthesis and Excellent Electromagnetic Absorption Properties

被引:330
作者
Ren, Yu-Lan [1 ]
Wu, Hong-Yu [1 ]
Lu, Ming-Ming [3 ]
Chen, Yu-Jin [1 ]
Zhu, Chun-Ling [2 ]
Gao, Peng [2 ]
Cao, Mao-Sheng [3 ]
Li, Chun-Yan [1 ]
Ouyang, Qiu-Yun [1 ]
机构
[1] Harbin Engn Univ, Coll Sci, Harbin, Peoples R China
[2] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin, Peoples R China
[3] Beijing Inst Technol, Sch Mat Sci & Engn, Beijing 100081, Peoples R China
基金
中国国家自然科学基金;
关键词
graphene; Fe3O4; Fe; ZnO; quaternary nanocomposites; electromagnetic absorption; CORE/SHELL NANORODS SYNTHESIS; MICROWAVE-ABSORPTION; ANODE MATERIAL; REVERSIBLE CAPACITY; TERNARY COMPOSITES; PERMITTIVITY; NANOSHEETS; OXIDE; PERMEABILITY; NANOTUBES;
D O I
10.1021/am3021697
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
This paper presents for the first time a successful synthesis of quaternary nanocomposites consisting of graphene, Fe3O4@Fe core/shell nanopariticles, and ZnO nanoparticles. Transmission electron microscopy measurements show that the diameter of the Fe3O4@Fe core/shell nanoparitcles is about 18 nm, the Fe3O4 shell's thickness is about 5 nm, and the diameter of ZnO nanoparticles is in range of 2-10 nm. The measured electromagnetic parameters show that the absorption bandwidth with reflection loss less than 20 dB is up to 7.3 GHz, and in the band range more than 99% of electromagnetic wave energy is attenuated. Moreover, the addition amount of the nanocomposites in the matrix is only 20 wt %. Therefore, the excellent electromagnetic absorption properties with lightweight and wide absorption frequency band are realized by the nanocomposites.
引用
收藏
页码:6436 / 6442
页数:7
相关论文
共 55 条
[1]   Multi layered Nanoarchitecture of Graphene Nanosheets and Polypyrrole Nanowires for High Performance Supercapacitor Electrodes [J].
Biswas, Sanjib ;
Drzal, Lawrence T. .
CHEMISTRY OF MATERIALS, 2010, 22 (20) :5667-5671
[2]   A Facile One-step Method to Produce Graphene-CdS Quantum Dot Nanocomposites as Promising Optoelectronic Materials [J].
Cao, Aoneng ;
Liu, Zhen ;
Chu, Saisai ;
Wu, Minghong ;
Ye, Zhangmei ;
Cai, Zhengwei ;
Chang, Yanli ;
Wang, Shufeng ;
Gong, Qihuang ;
Liu, Yuanfang .
ADVANCED MATERIALS, 2010, 22 (01) :103-+
[3]   L-Cysteine-Assisted Synthesis of Layered MoS2/Graphene Composites with Excellent Electrochemical Performances for Lithium Ion Batteries [J].
Chang, Kun ;
Chen, Weixiang .
ACS NANO, 2011, 5 (06) :4720-4728
[4]   Graphene-like MoS2/amorphous carbon composites with high capacity and excellent stability as anode materials for lithium ion batteries [J].
Chang, Kun ;
Chen, Weixiang ;
Ma, Lin ;
Li, Hui ;
Li, He ;
Huang, Feihe ;
Xu, Zhude ;
Zhang, Qingbo ;
Lee, Jim-Yang .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (17) :6251-6257
[5]   Fabrication and microwave absorption of carbon nanotubes/CoFe2O4 spinel nanocomposite -: art. no. 033105 [J].
Che, RC ;
Zhi, CY ;
Liang, CY ;
Zhou, XG .
APPLIED PHYSICS LETTERS, 2006, 88 (03) :1-3
[6]   Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes [J].
Che, RC ;
Peng, LM ;
Duan, XF ;
Chen, Q ;
Liang, XL .
ADVANCED MATERIALS, 2004, 16 (05) :401-+
[7]   Graphene-Encapsulated Hollow Fe3O4 Nanoparticle Aggregates As a High-Performance Anode Material for Lithium Ion Batteries [J].
Chen, Dongyun ;
Ji, Ge ;
Ma, Yue ;
Lee, Jim Yang ;
Lu, Jianmei .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (08) :3078-3083
[8]   Graphene Oxide-MnO2 Nanocomposites for Supercapacitors [J].
Chen, Sheng ;
Zhu, Junwu ;
Wu, Xiaodong ;
Han, Qiaofeng ;
Wang, Xin .
ACS NANO, 2010, 4 (05) :2822-2830
[9]   Synthesis, magnetic and electromagnetic wave absorption properties of porous Fe3O4/Fe/SiO2 core/shell nanorods [J].
Chen, Y. J. ;
Gao, P. ;
Zhu, C. L. ;
Wang, R. X. ;
Wang, L. J. ;
Cao, M. S. ;
Fang, X. Y. .
JOURNAL OF APPLIED PHYSICS, 2009, 106 (05)
[10]   Microwave absorption properties of the ZnO nanowire-polyester composites [J].
Chen, YJ ;
Cao, MS ;
Wang, TH ;
Wan, Q .
APPLIED PHYSICS LETTERS, 2004, 84 (17) :3367-3369