Efficient small molecule bulk heterojunction solar cells with high fill factors via introduction of π-stacking moieties as end group

被引:98
作者
He, Guangrui [1 ,2 ]
Li, Zhi [1 ,2 ]
Wan, Xiangjian [1 ,2 ]
Zhou, Jiaoyan [1 ,2 ]
Long, Guankui [1 ,2 ]
Zhang, Shuzhong [3 ]
Zhang, Mingtao [4 ]
Chen, Yongsheng [1 ,2 ]
机构
[1] Nankai Univ, Coll Chem, Key Lab Funct Polymer Mat, Tianjin 300071, Peoples R China
[2] Nankai Univ, Coll Chem, Inst Polymer Chem, Ctr Nanoscale Sci & Technol, Tianjin 300071, Peoples R China
[3] Nankai Univ, State Key Lab Elementoogran Chem, Tianjin 300071, Peoples R China
[4] Nankai Univ, Computat Ctr Mol Sci, Tianjin 300071, Peoples R China
关键词
PROCESSED SMALL-MOLECULE; POWER-CONVERSION EFFICIENCY; ORGANIC PHOTOVOLTAIC CELLS; OPEN-CIRCUIT VOLTAGE; POLYMER; PERFORMANCE; MORPHOLOGY; SEMICONDUCTORS; GENERATION;
D O I
10.1039/c2ta00496h
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Three new oligothiophene derivatives with an acceptor-donor-acceptor structure incorporating 1,3-indanedione or the derivative of 1,3-indanedione units as the terminal acceptor groups-DIN7T, DINCN7T and DDIN7T-have been designed and synthesized for solution-processable small molecule BHJ solar cells. The impacts of these different end dye moieties on the optical absorption, solubility, electrochemical properties, morphology, mobility and solar cell performance were studied. All three compounds exhibit broad and highly efficient solar absorption with a low bandgap. The DIN7T-based BHJ solar cell device achieved a PCE of 4.93% and a high fill factor of 0.72, under illumination of AM 1.5, 100 mW cm(-2).
引用
收藏
页码:1801 / 1809
页数:9
相关论文
共 56 条
[31]   Electrochemical properties of luminescent polymers and polymer light-emitting electrochemical cells [J].
Li, YF ;
Cao, Y ;
Gao, J ;
Wang, DL ;
Yu, G ;
Heeger, AJ .
SYNTHETIC METALS, 1999, 99 (03) :243-248
[32]   Molecular Design of Photovoltaic Materials for Polymer Solar Cells: Toward Suitable Electronic Energy Levels and Broad Absorption [J].
Li, Yongfang .
ACCOUNTS OF CHEMICAL RESEARCH, 2012, 45 (05) :723-733
[33]   Solution Processable Rhodanine-Based Small Molecule Organic Photovoltaic Cells with a Power Conversion Efficiency of 6.1% [J].
Li, Zhi ;
He, Guangrui ;
Wan, Xiangjian ;
Liu, Yongsheng ;
Zhou, Jiaoyan ;
Long, Guankui ;
Zuo, Yi ;
Zhang, Mingtao ;
Chen, Yongsheng .
ADVANCED ENERGY MATERIALS, 2012, 2 (01) :74-77
[34]   Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties [J].
Liang, Yongye ;
Feng, Danqin ;
Wu, Yue ;
Tsai, Szu-Ting ;
Li, Gang ;
Ray, Claire ;
Yu, Luping .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (22) :7792-7799
[35]   BODIPY dyes with β-conjugation and their applications for high-efficiency inverted small molecule solar cells [J].
Lin, Hsin-Yu ;
Huang, Wei-Ching ;
Chen, Yung-Chung ;
Chou, Hsien-Hsin ;
Hsu, Chih-Yu ;
Lin, Jiann T. ;
Lin, Hao-Wu .
CHEMICAL COMMUNICATIONS, 2012, 48 (71) :8913-8915
[36]   Small molecule semiconductors for high-efficiency organic photovoltaics [J].
Lin, Yuze ;
Li, Yongfang ;
Zhan, Xiaowei .
CHEMICAL SOCIETY REVIEWS, 2012, 41 (11) :4245-4272
[37]   High-Performance Solar Cells using a Solution-Processed Small Molecule Containing Benzodithiophene Unit [J].
Liu, Yongsheng ;
Wan, Xiangjian ;
Wang, Fei ;
Zhou, Jiaoyan ;
Long, Guankui ;
Tian, Jianguo ;
Chen, Yongsheng .
ADVANCED MATERIALS, 2011, 23 (45) :5387-+
[38]   Spin-Coated Small Molecules for High Performance Solar Cells [J].
Liu, Yongsheng ;
Wan, Xiangjian ;
Wang, Fei ;
Zhou, Jiaoyan ;
Long, Guankui ;
Tian, Jianguo ;
You, Jingbi ;
Yang, Yang ;
Chen, Yongsheng .
ADVANCED ENERGY MATERIALS, 2011, 1 (05) :771-775
[39]   Efficient solution processed bulk-heterojunction solar cells based a donor-acceptor oligothiophene [J].
Liu, Yongsheng ;
Wan, Xiangjian ;
Yin, Bin ;
Zhou, Jiaoyan ;
Long, Guankui ;
Yin, Shougen ;
Chen, Yongsheng .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (12) :2464-2468
[40]   Synthesis and properties of acceptor-donor-acceptor molecules based on oligothiophenes with tunable and low band gap [J].
Liu, Yongsheng ;
Zhou, Jiaoyan ;
Wan, Xiangjian ;
Chen, Yongsheng .
TETRAHEDRON, 2009, 65 (27) :5209-5215