Photocatalytic Activity Enhanced via g-C3N4 Nanoplates to Nanorods

被引：636

作者：

Bai, Xiaojuan ^{[1
]}

Wang, Li ^{[1
]}

Zong, Ruilong ^{[1
]}

Zhu, Yongfa ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Beijing Key Lab Analyt Methods & Instrumentat, Beijing 100084, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2013年 / 117卷 / 19期

基金：

美国国家科学基金会; 国家高技术研究发展计划(863计划);

关键词：

GRAPHITIC CARBON NITRIDE; VISIBLE-LIGHT-DRIVEN; HYDROGEN-PRODUCTION; WATER; PERFORMANCES; DEGRADATION; OXIDATION; CATALYST; ZNWO4; O-2;

D O I：

10.1021/jp402062d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The transformation of graphitic carbon nitride (g-C3N4) from nanoplates to nanorods was realized by a simple reflux method. The photocatalytic activity and the intensity of the, photocurrent response of g-C3N4 nanorods under visible light were about 1.5 and 2.0 times those of g-C3N4 nanoplates, respectively. The formation mechanism of g-C3N4 from nanoplates to nanorods was demonstrated that g-C3N4 nanoplates undergo,a possible exfoliation and regrowth process and a rolling mechanism of lamellar structure, which is responsible for elimination of the surface defects in the reflux process. During the transformation of g-C3N4 from nanoplates to nanorods, the enhancement of photocatalytic activity and photocurrent intensity in g-C3N4 nanorods was mainly attributed to the increase of active lattice face and elimination of surface defects.

引用

页码：9952 / 9961

页数：10

共 56 条

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