A chiral M6L4 cage complex assembled from a D2h-symmetric ligand:: Self-assembly, structure, and chirality observation

被引：23

作者：

Kubota, Y

Biradha, K

Fujita, M

Sakamoto, S

Yamaguchi, K

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Appl Chem, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Chiba Univ, Ctr Chem Anal, Chiba 2638522, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2002年 / 75卷 / 03期

关键词：

D O I：

10.1246/bcsj.75.559

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral M6L4 cage structures were self-assembled by mixing a D-2h-symmetric ligand with a cis end-capped (diamine)Pd(NO3)(2) complex [diamine = ethylenediamine (en), 2,2'-bipyridine (2,2-bpy), or 1,2-cyclohexanediamine (cxn)]. This self-assembly was achieved by exploiting the template effect of an aromatic guest molecule. The structures were confirmed by CSI-MS, NMR observations, and X-ray crystallographic analysis. Having C-2 molecular chirality, two diastereomers were differentiated by attaching a chiral auxiliary on Pd(II).

引用

页码：559 / 565

页数：7

共 47 条

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