A new combination of donor and acceptor:: bis(η6-benzene)chromium and hexafluorobenzene form a charge-transfer stacked crystal

被引：47

作者：

Aspley, CJ

Boxwell, C

Buil, ML

Higgitt, CL

Long, C

Perutz, RN ^{[1
]}

机构：

[1] Univ York, Dept Chem, York YO10 5DD, N Yorkshire, England

[2] Dublin City Univ, Dept Chem, Dublin 9, Ireland

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 11期

关键词：

D O I：

10.1039/a900919a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(eta(6)-benzene)chromium reacts with hexafluorobenzene to yield a red charge-transfer complex [Cr(eta(6)-C6H6)(2). C6F6] which contains stacks of alternating donor and acceptor molecules with close inter- and intrastack contacts; in addition to the charge-transfer complex, formation of [Cr(eta(6)-C6H6)(2)](+) is demonstrated by EPR and IR spectroscopy.

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页码：1027 / 1028

页数：2

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