Demonstration of a high precision optical probe for effective sampling of solids by Raman spectroscopy.

被引：10

作者：

Marquardt, BJ ^{[1
]}

Le, T ^{[1
]}

Burgess, LW ^{[1
]}

机构：

[1] Univ Washington, Ctr Proc Analyt Chem, Dept Chem, Seattle, WA 98195 USA

来源：

RAMAN SPECTROSCOPY AND LIGHT SCATTERING TECHNOLOGIES IN MATERIALS SCIENCE | 2001年 / 4469卷

关键词：

Raman; fiber optics; immersion probe; sampling; process analysis; slurries; powders;

D O I：

10.1117/12.447374

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

This presentation will focus on the development, optimization and use of a Raman spectroscopy immersion probe for the analysis of solid (powders, slurries, etc.) samples with emphasis on online process analysis applications. A novel high precision Raman probe for online process analysis will be described. The unique design of the Raman probe provides enhancements in measurement precision by increasing the reproducibility and accuracy of optical sampling of high solids content samples. The probe has been proven an effective sampling interface for the analysis of powders, suspensions, slurries, particles and solids. The ease of use of the Raman probe and the increased sampling precision has lead to its use in various proof of concept and online process analytical applications. These applications include dry powder-powder mixing efficiency, coating thickness measurements, solvent drying analysis, reaction monitoring and many other analytical processes. The physical and optical design of the Raman probe will be described and the applicability of the Raman probe as an online sampling tool will be demonstrated.

引用

页码：62 / 69

页数：8

共 19 条

[1] NEAR-INFRARED RAMAN-SPECTROSCOPY OF LIQUIDS AND SOLIDS WITH A FIBEROPTIC SAMPLER, DIODE-LASER, AND CCD DETECTOR [J].

ALLRED, CD ;

MCCREERY, RL .

APPLIED SPECTROSCOPY, 1990, 44 (07) :1229-1231

[2]

Angel SM, 1999, J RAMAN SPECTROSC, V30, P795, DOI 10.1002/(SICI)1097-4555(199909)30:9<795::AID-JRS451>3.0.CO

[3]

2-2

[4] In situ analysis of a high-temperature cure reaction in real time using modulated fiber-optic FT-Raman spectroscopy [J].

Aust, JF ;

Cooper, JB ;

Wise, KL ;

Jensen, BJ .

APPLIED SPECTROSCOPY, 1999, 53 (06) :682-686

[5] Comparative study of some fiber-optic remote Raman probe designs .2. Tests of single-fiber, lensed, and flat- and bevel-tip multi-fiber probes [J].

Cooney, TF ;

Skinner, HT ;

Angel, SM .

APPLIED SPECTROSCOPY, 1996, 50 (07) :849-860

[6] RARE-EARTH-DOPED GLASS-FIBER FOR BACKGROUND REJECTION IN REMOTE FIBEROPTIC RAMAN PROBES - THEORY AND ANALYSIS OF HOLMIUM-BEARING GLASS [J].

COONEY, TF ;

SCHOEN, CL ;

SHARMA, SK ;

CAREY, DM .

APPLIED SPECTROSCOPY, 1993, 47 (10) :1683-1692

[7] Comparative study of some fiber-optic remote Raman probe designs .1. Model for liquids and transparent solids [J].

Cooney, TF ;

Skinner, HT ;

Angel, SM .

APPLIED SPECTROSCOPY, 1996, 50 (07) :836-848

[8] ACCURATE PROCEDURE FOR DETERMINING THE CALIBRATION CURVE OF HIGH-TEMPERATURE MOLTEN-SALT SYSTEMS VIA RAMAN-SPECTROSCOPY [J].

DAI, S ;

MAMANTOV, G ;

COFFIELD, JE ;

BEGUN, GM ;

YOUNG, JP .

APPLIED SPECTROSCOPY, 1993, 47 (08) :1286-1288

[9] TEMPERATURE-MEASUREMENT BY OBSERVATION OF THE RAMAN-SPECTRUM OF DIAMOND [J].

DAI, S ;

YOUNG, JP ;

BEGUN, GM ;

MAMANTOV, G .

APPLIED SPECTROSCOPY, 1992, 46 (02) :375-377

[10] QUANTITATIVE DETECTION OF ENVIRONMENTALLY IMPORTANT DYES USING DIODE LASER/FIBER-OPTIC RAMAN-SPECTROSCOPY [J].

GILMORE, DA ;

GURKA, D ;

DENTON, MB .

APPLIED SPECTROSCOPY, 1995, 49 (04) :508-512

← 1 2 →