Expression of the prohelicity of bis-cyclomanganated 2,3-diphenylquinoxaline through reactions with diaryldiazomethanes

被引：14

作者：

de Cian, A

Djukic, JP

Fischer, J

Pfeffer, M

Dötz, KH

机构：

[1] Univ Strasbourg 1, CNRS, UMR 7513, F-67070 Strasbourg, France

[2] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 06期

关键词：

D O I：

10.1039/b111570g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of bis-cyclomanganated 2,3-diphenylquinoxaline with diazodiphenylmethane and 9-diazofluorene allowed the formation of a new oligomeric and dinuclear manganospiralene and the ready preparation of a pentacyclic helix comprising two (eta(5)-fluorenyl)Mn(CO)(3) fragments, whose helicity can be locked upon one-dimensional linear coordination to silver cation.

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收藏

页码：638 / 639

页数：2

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