Iridium-catalyzed asymmetric hydrosilylation of imines using chiral oxazolinyl-phosphine ligands

被引：73

作者：

Takei, I

Nishibayashi, Y

Arikawa, Y

Uemura, S ^{[1
]}

Hidai, M

机构：

[1] Univ Tokyo, Grad Sch Engn, Dept Chem & Biotechnol, Tokyo 1138656, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

来源：

ORGANOMETALLICS | 1999年 / 18卷 / 11期

关键词：

D O I：

10.1021/om981005w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chiral oxazolinylphosphines are effective ligands for the Ir(I)-catalyzed asymmetric hydrosilylation of imines to afford the corresponding sec-amines with high enantioselectivities (up to 89% ee) after hydrolysis in almost quantitative yields. The structure of an Ir(I)-oxazolinylferrocenylphosphine complex was determined by X-ray analysis.

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页码：2271 / 2274

页数：4

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