Catalytic asymmetric hydrosilylation of ketones using rhodium-(I)-complexes of chiral phosphinooxazoline ligands

被引：81

作者：

Langer, T ^{[1
]}

Janssen, J ^{[1
]}

Helmchen, G ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ORGAN CHEM,D-69120 HEIDELBERG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 06期

关键词：

D O I：

10.1016/0957-4166(96)00192-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(Phosphinooxazoline)rhodium(I) complexes, prepared in situ with ligand:Rh molar ratio of 1.3:1, were applied as catalysts in hydrosilylations of a variety of ketones to yield secondary alcohols with moderate to good enantioselectivities. (C) 1996 Elsevier Science Ltd

引用

页码：1599 / 1602

页数：4

共 18 条

[1] [Anonymous], ASYMMETRIC SYNTHESIS
[2] ENANTIOSELECTIVE CATALYSIS .94. THE DIPHENYL EFFECT IN THE ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH DIPHENYLSILANE USING RH/5,5-DIPHENYL-2-(2-PYRIDINYL)OXAZOLINE CATALYSTS
BRUNNER, H
HENRICHS, C
[J]. TETRAHEDRON-ASYMMETRY, 1995, 6 (03) : 653 - 656
[3] BRUNNER H, 1995, STEREOSELECTIVE SY E, V21, P4074
[4] ENANTIOSELECTIVE HYDROSILYLATION OF KETONES WITH L-ASTERISK/[RH(COD)CL]2 AND L-ASTERISK/[IR(COD)CL]2 CATALYSTS (L-ASTERISK=PH2P(O)NCH2CH(NME2)(CH2)MSME (N=0, 1, M=1,2))
FALLER, JW
CHASE, KJ
[J]. ORGANOMETALLICS, 1994, 13 (03) : 989 - 992
[5] CATALYTIC ASYMMETRIC HYDROSILATION OF ARYL ALKYL KETONES WITH C-2-SYMMETRICAL CHIRAL METALLOCENE COMPLEXES
HALTERMAN, RL
RAMSEY, TM
CHEN, ZL
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (09) : 2642 - 2644
[6] HELMCHEN G, 1991, SYNLETT, P257
[7] HYASHI T, 1995, TETRAHEDRON-ASYMMETR, V6, P2503
[8] ITO Y, 1994, ANGEW CHEM, V106, P92
[9] ITO Y, 1995, SYNLETT, P347
[10] ITO Y, 1994, ANGEW CHEM, V33, P111

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