ENANTIOSELECTIVE CATALYSIS .94. THE DIPHENYL EFFECT IN THE ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH DIPHENYLSILANE USING RH/5,5-DIPHENYL-2-(2-PYRIDINYL)OXAZOLINE CATALYSTS

被引：34

作者：

BRUNNER, H

HENRICHS, C

机构：

[1] Institut für Anorganische Chemie, Universität Regensburg

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 03期

关键词：

D O I：

10.1016/0957-4166(95)00052-Q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 5,5-diphenyl-2-(2-pyridinyl)oxazolines 2a-e give ee values 9.6 - 34.2 % higher than their unsubstituted counterparts 1a-e in the Rh-catalyzed enantioselective hydrosilylation of acetophenone with diphenylsilane.

引用

页码：653 / 656

页数：4

共 21 条

[1] ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH RHODIUM OXAZOLINES CATALYSTS
BALAVOINE, G
CLINET, JC
LELLOUCHE, I
[J]. TETRAHEDRON LETTERS, 1989, 30 (38) : 5141 - 5144
[2] ASYMMETRICAL CATALYSTS .32. ENANTIOSELECTIVE PHENYLATION OF CIS-CYCLOHEXANE-1,2-DIOL AND MESO-BUTANE-2,3-DIOL
BRUNNER, H
OBERMANN, U
WIMMER, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 316 (1-2) : C1 - C3
[3] ASYMMETRIC CATALYSIS .45. ENANTIOSELECTIVE HYDROSILYLATION OF KETONES WITH [RH(COD)CL]2/PYRIDINYLOXAZOLINE CATALYSTS
BRUNNER, H
OBERMANN, U
[J]. CHEMISCHE BERICHTE-RECUEIL, 1989, 122 (03): : 499 - 507
[4] ENANTIOSELECTIVE CATALYSIS .74. LIGAND EXCESS AND INTERMEDIATES IN THE RHODIUM-CATALYZED ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH PYRIDINEOXAZOLINE LIGANDS
BRUNNER, H
BRANDL, P
[J]. TETRAHEDRON-ASYMMETRY, 1991, 2 (09) : 919 - 930
[5] BRUNNER H, 1992, Z NATURFORSCH B, V47, P609
[6] ASYMMETRIC CATALYSIS .56. ENANTIOSELECTIVE HYDROSILYLATION OF ACETOPHENONE WITH A RHODIUM PICOLINEOXAZOLINE CATALYST 1-1
BRUNNER, H
BRANDL, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 390 (03) : C81 - C83
[7] BRUNNER H, 1991, Z NATURFORSCH B, V46, P1145
[8] BRUNNER H, 1993, CATALYTIC ASYMMETRIC, P303
[9] BRUNNER H, IN PRESS SYNTHESIS
[10] ASYMMETRIC PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION USING PHOSPHORUS-CONTAINING OXAZOLINE LIGANDS
DAWSON, GJ
FROST, CG
WILLIAMS, JMJ
[J]. TETRAHEDRON LETTERS, 1993, 34 (19) : 3149 - 3150

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