Ferrocene-appended porphyrins: Syntheses and properties

被引：132

作者：

Bucher, Christophe ^{[1
]}

Devillers, Charles H. ^{[1
]}

Moutet, Jean-Claude ^{[1
]}

Royal, Guy ^{[1
]}

Saint-Aman, Eric ^{[1
]}

机构：

[1] Univ Grenoble 1, Lab Chim Organ Redox, Dept Chim Mol, UMR CNRS UJF 5250, F-38041 Grenoble 9, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 1-2期

关键词：

Ferrocene; Porphyrins; PHOTOINDUCED ELECTRON-TRANSFER; SELF-ASSEMBLED MONOLAYERS; THIOL LINKED MOLECULE; HIGH QUANTUM YIELD; CHARGE SEPARATION; MESO-TETRAFERROCENYLPORPHYRIN; FULLERENE TRIADS; BETA; BETA'-FUSED METALLOCENOPORPHYRINS; ELECTROCHEMICAL PROPERTIES; FUNCTIONALIZED PORPHYRINS;

D O I：

10.1016/j.ccr.2007.11.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review article focuses on the syntheses and potential applications of ferrocene-appended porphyrin architectures. Several strategies have been developed to date to associate ferrocenyl fragments and porphyrin rings in the same molecular architecture, depending on the targeted application: (i) connection at a meso position through a direct linkage, a conjugated or saturated spacer or using a non-covalent approach and (ii) connection at a beta-pyrrolic position. Examples of ferrocene-porphyrin analogues are also presented. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：21 / 36

页数：16

共 116 条

[1]

Abramova, 2005, UKR KHIM ZH, V71, P79

[2] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].