In situ cryo-crystallization of fluorinated amines: A comparative study of cooperative intermolecular interactions involving ordered and disordered fluorine

被引:38
作者
Chopra, D [1 ]
Thiruvenkatam, V [1 ]
Row, TNG [1 ]
机构
[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
关键词
D O I
10.1021/cg060053d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The low-temperature crystal structures of 4-fluoroaniline and 2-fluoroaniline, determined following in situ crystal growth from the liquid, reveal the importance of both strong hydrogen bonds and weak intermolecular interactions involving fluorine generating different packing motifs in the crystalline solid in the isomeric molecules.
引用
收藏
页码:843 / 845
页数:3
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