Chemistry in motion -: Unidirectional rotating molecular motors

被引：64

作者：

Mandl, CP ^{[1
]}

König, B ^{[1
]}

机构：

[1] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 13期

关键词：

catenanes; isomerization; macrocycles; photochemistry;

D O I：

10.1002/anie.200301697

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Clockwise or counterclockwise? On the molecular level this is determined by kinetic control of the competing routes to the new energetically minimized structure. Three recent examples show how this can be achieved. The picture shows a molecular rotor whose large macrocycle contains three binding sites between which the small macrocycle moves.

引用

页码：1622 / 1624

页数：3

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