Water-promoted Suzuki reaction in room temperature ionic liquids

被引：42

作者：

Xin, BW

Zhang, YH ^{[1
]}

Liu, LF

Wang, YG

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

[2] Dezhou Univ, Dept Chem, Dezhou 253023, Peoples R China

来源：

SYNLETT | 2005年 / 20期

关键词：

Suzuki reaction; ionic liquid; palladium acetate;

D O I：

10.1055/s-2005-922756

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Suzuki reaction was successfully performed by using Pd(OAc)(2) as the catalyst in a mixture of water and ionic liquids in a short reaction time in air. Water was found to have a remarkable rate accelerating effect on the Suzuki reaction in ionic liquids. The Pd(OAc)(2)-[bmim] [PF6] can be reused seven times only with a small deactivation of reactivity.

引用

收藏

页码：3083 / 3086

页数：4

相关论文

共 41 条

[1] Highly efficient palladium-catalyzed boronic acid coupling reactions in water: Scope and limitations [J].

Badone, D ;

Baroni, M ;

Cardamone, R ;

Ielmini, A ;

Guzzi, U .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (21) :7170-7173

[2] Application of the palladium-catalyzed borylation/Suzuki coupling (BSC) reaction to the synthesis of biologically active biaryl lactams [J].

Baudoin, O ;

Cesario, M ;

Guénard, D ;

Guéritte, F .

JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (04) :1199-1207

[3] The Suzuki coupling of aryl chlorides in TBAB-water mixtures [J].

Bedford, RB ;

Blake, ME ;

Butts, CP ;

Holder, D .

CHEMICAL COMMUNICATIONS, 2003, (04) :466-467

[4] Pd nanoparticles as efficient catalysts for Suzuki and Stille coupling reactions of aryl halides in ionic liquids [J].

Calò, V ;

Nacci, A ;

Monopoli, A ;

Montingelli, F .

JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (15) :6040-6044

[5] An imidazolium ionic liquid having covalently attached an oxime carbapalladacycle complex as ionophilic heterogeneous catalysts for the Heck and Suzuki-Miyaura cross-coupling [J].

Corma, A ;

García, H ;

Leyva, A .

TETRAHEDRON, 2004, 60 (38) :8553-8560

[6] Ionic liquid (molten salt) phase organometallic catalysis [J].

Dupont, J ;

de Souza, RF ;

Suarez, PAZ .

CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691

[7] Ionic liquids. Green solvents for the future [J].

Earle, MJ ;

Seddon, KR .

PURE AND APPLIED CHEMISTRY, 2000, 72 (07) :1391-1398

[8]

Herrmann WA, 2002, ANGEW CHEM INT EDIT, V41, P1290, DOI 10.1002/1521-3773(20020415)41:8<1290::AID-ANIE1290>3.0.CO

[9]

2-Y

[10]

Herrmann WA, 1998, J ORGANOMET CHEM, V557, P93

← 1 2 3 4 5 →