Competitive adsorption of ternary dye mixture using pine cone powder modified with β-cyclodextrin

被引:71
作者
Debnath, Sushanta [1 ,2 ]
Ballav, Niladri [1 ]
Maity, Arjun [1 ,3 ]
Pillay, Kriveshini [1 ]
机构
[1] Univ Johannesburg, Dept Appl Chem, Johannesburg, South Africa
[2] Saha Inst Nucl Phys, C&MB Div, Kolkata, India
[3] CSIR, Natl Ctr Nano structured Mat, Pretoria, South Africa
关键词
Pine cone; beta-cyclodextrin; Competitive adsorption; Ternary dye mixture; AQUEOUS-SOLUTION; ACTIVATED CARBON; MALACHITE GREEN; METHYLENE-BLUE; ENHANCED ADSORPTION; BASIC-DYES; ACID DYES; CATIONIC DYES; SAFRANIN-O; REMOVAL;
D O I
10.1016/j.molliq.2016.10.109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
The adsorption characteristics for the uptake of a ternary dye mixture safranine 0, brilliant green and methylene blue (SO, BG and MB) by pine cone modified with beta-cyclodextrin (CD) were investigated. The adsorption process primarily followed a pseudo - second order model and the rate of adsorption was inversely proportional to the initial dye concentration. The adsorption was also a multi-stage process which was limited by intraparticle diffusion. The adsorption predominately followed the Langmuir isotherm and was controlled by physisorption and electrostatic interactions. The adsorption was spontaneous and endothermic in nature. The order of performance of adsorption of the dyes was BG>SO> MB at all temperatures studied. The adsorption of BG was therefore highly favoured at all temperatures. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:679 / 688
页数:10
相关论文
共 63 条
[1]
Competitive adsorption of reactive dyes from solution: Equilibrium isotherm studies in single and multisolute systems [J].
Al-Degs, Y. ;
Khraisheh, M. A. M. ;
Allen, S. J. ;
Ahmad, M. N. ;
Walker, G. M. .
CHEMICAL ENGINEERING JOURNAL, 2007, 128 (2-3) :163-167
[2]
Aljebori A. M., 2014, ARAB J CHEM
[3]
INTRAPARTICLE DIFFUSION OF A BASIC DYE DURING ADSORPTION ONTO SPHAGNUM PEAT [J].
ALLEN, SJ ;
MCKAY, G ;
KHADER, KYH .
ENVIRONMENTAL POLLUTION, 1989, 56 (01) :39-50
[4]
[Anonymous], 1963, J. Sanit. Eng. Div. Am. Soc. Civ. Eng, DOI DOI 10.1061/JSEDAI.0000430
[5]
Point of zero charge and intrinsic equilibrium constants of activated carbon cloth [J].
Babic, BM ;
Milonjic, SK ;
Polovina, MJ ;
Kaludierovic, BV .
CARBON, 1999, 37 (03) :477-481
[6]
Interaction between graphite oxide and Congo red in aqueous media [J].
Barkauskas, Jurgis ;
Stankeviciene, Inga ;
Daksevic, Justina ;
Padarauskas, Audrius .
CARBON, 2011, 49 (15) :5373-5381
[7]
Error Analysis of Adsorption Isotherm Models for Acid Dyes onto Bamboo Derived Activated Carbon [J].
Chan, L. S. ;
Cheung, W. H. ;
Allen, S. J. ;
McKay, G. .
CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2012, 20 (03) :535-542
[8]
Enhanced adsorption of congo red from aqueous solutions by chitosan hydrogel beads impregnated with cetyl trimethyl ammonium bromide [J].
Chatterjee, Sudipta ;
Lee, Dae S. ;
Lee, Min W. ;
Woo, Seung H. .
BIORESOURCE TECHNOLOGY, 2009, 100 (11) :2803-2809
[9]
Surface modification of a granular activated carbon by citric acid for enhancement of copper adsorption [J].
Chen, JP ;
Wu, SN ;
Chong, KH .
CARBON, 2003, 41 (10) :1979-1986
[10]
Kinetic studies on the adsorption of methylene blue onto vegetal fiber activated carbons [J].
Cherifi, Hakima ;
Fatiha, Bentahar ;
Salah, Hanini .
APPLIED SURFACE SCIENCE, 2013, 282 :52-59